This single-crystal x-ray diffractometer is used for determining 3D structure from single crystals. With dual micro-focus sources (Cu and Mo), the D8 Venture can collect on a variety of samples, such as solid-state inorganics, organometallics, organics, metal-organic frameworks, proteins, peptides, etc.

The Photon III CPAD area detector supports both photon counting and charge integration for improved sensitivity and dynamic range and provides real-time data processing while operating in shutterless data acquisition mode for fast data collection. Researchers can submit samples for analysis or undergo training.

Location

A. Paul Schaap Chemistry Building, Room 50.1

Statement of acknowledgment

The D8 Venture was funded through a National Institutes of Health (NIH) supplement grant. Please acknowledge the use of this instrument in your publications, presentations, and dissertations. A suggested statement can read: "This work made use of the single-crystal XRD that is funded by the National Institutes of Health supplement grant #3R01EB027103-02S1."

Publications

• Bokouende, S. S.; Kulasekara, D. N.; Worku, S. A.; Ward, C. L.; Kajjam, A. B.; Lutter, J. C.; Allen, M. J. “Expanding the Coordination of f-block metals with tris[2-(2-methoxy-ethoxy)ethyl]amine: from Molecular Complexes to Cage-Like Structures” Inorganic Chemistry, 2023, doi.org/10.1021/acs.inorgchem.3c02752
• Don, U. I. K.; Palmer, Z.; Ward, C. L.; Lord, R. L.; Groysman, S. “Combining [Mo^VIO₃] and [M⁰(CO)₃] (M = Mo, Cr) Fragments Within the Same Complex: Synthesis and Reactivity of the Single Oxo-bridged Heterobimetallics Supported by Xanthene-Based Heterodinucleating Ligands,” Inorganic Chemistry, 2023, 62, 15063
• Jayakodiarachchi, N.; Liu, R.; Dharmadasa, C.; Hu, X.; Savage, D. E.; Ward, C. L.; Evans, P. G.; Winter, C. H. “Thermal Atomic Layer Deposition of Er₂O₃ Films from a Volatile, Thermally Stable Enaminolate Precursor,” Dalton Transactions, 2023, 52, 11096
• Don, U. I. K.; Almaat, A. S.; Ward, C. L.; Groysman, S. “Studies Relevant to the Functional Model of Mo-Cu CODH: In Situ Reactions of Cu(I)-L Complexes with Mo(VI) and Synthesis of Stable Structurally Characterized Heterotetranuclear Mo^VI₂Cu^I₂ Complex,” Molecules, 2023, 28  3644
• Subasinghe, S. A. A. S.; Ortiz, C. J.; Romero, J.; Ward, C. L.; Sertage, A. G.; Yustein, J. T.; Pautler, R. G.; Allen, M. J. “Toward Quantification of Hypoxia using Fluorinated Eu^II/III-containing Ratiometric Probes,” Proceedings of the National Academy of Sciences, 2023, 120, (15) e2220891120
• Munasinghe, H. N.; Imer, M. R.; Szlag, R. G.; Suescun, L.; Rabuffetti, F. A. "Reactivity of bi-and monometallic trifluoroacetates towards amorphous SiO₂," Dalton Transactions, 2022, 51, 18224
• Barraza Jr., R.; Sertage, A.; Ward, C. L.; Schlegel, H. B.; Allen, M. J. “Properties of Amine-Containing Ligands that are Necessary for Visible-Light-Promoted Catalysis with Divalent Europium,” Inorganic Chemistry, 2022, 61, 19649
• Gupta, S.; Ward, C. L.; Perera, S. S.; Gowan, C. T.; Dittrich, T. M.; Allen, M. J.; McElmurry, S. P.; Kodanko, J. J. “Development of a highly selective Ni(II) chelator in aqueous solution,” Inorganic Chemistry, 2022 61, 19492
• Bokouende, S. S.; Jenks, T. C.; Ward, C. L.; Allen, M. J.; “Solid-State and Solution-Phase Characterization of SmII-Aza[2.2.2]cryptate and Its Methylated Analogue,” Dalton Transactions, 2022, 51, 10852
• Kulasekara, D. N.; Ward, C. L.; Allen, M. J. CSD Communication 2022 DOI: 10.5517/ccdc.csd.cc2cyy1b
• Bokouende, S. S.; Ward, C. L.; Allen, M. J. CSD Communication 2022 DOI: 10.5517/ccdc.csd.cc2b4q9j
• Bokouende, S. S.; Ward, C. L.; Allen, M. J. CSD Communication 2022. DOI: 10.5517/ccdc.csd.cc2byhg8
• Gunasekara, D.; Mahajan, J. P.; Wanzi, Y.; Rodrigo, S.; Liu, W.; Tan, T.; Luo, L. “Controlling One- or Two-Electron Oxidation for Selective Amine Functionalization by Alternating Current Frequency”, Journal of the American Chemical Society, 2022, 22, 9874
• Munasinghe, H. N.; Szlag, R. G.; Imer, M. R.; Rabuffetti, F. A.; “Synthesis, Structure, and Luminescence of Mixed-Ligand Lanthanide Trifluoroacetates,” Inorganic Chemistry, 2022, 14, 5588